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Pro tips from the experts in Plumbing, Drains & Water Cleanup. Roto-Rooter presents: How to Clean a Sink Drain with Baking Soda & Vinegar. To unclog a drain without harsh chemicals, you'll need: 1/2 cup baking soda, 1 cup white vinegar, and hot water. Remove stopper, then pour baking soda down the drain and follow with vinegar. Wait 10 minutes, then carefully pour hot water down the drain. Replace stopper. All clean! ♪ Call Roto-Rooter, that's the name, and away go troubles down the drain. Roto-Rooter! ♪